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2.1.1 Narrative
The actions implemented during the reporting period included general site maintenance, ongoing water quality and flow monitoring; managing the settling ponds and associated historic lime precipitation solids; design and construction of a Site solids repository; evaluation and design of hydraulic control alternatives for the St. Louis Tunnel; water treatment demonstration scale system (EWD), design, construction, and testing; and the design of and beginning construction on an Enhanced Constructed Wetland Treatment System (ECWTS).
2.1.2 Response Actions to Date
The initial work at this Site was performed under a Unilateral Administrative Order that was issued in 2011 and is described in detail in the previous POLREPs. During the time between POLREP 5 (2/3/2016) and this POLREP, an Administrative Order on Consent was issued, superseding the UAO in all respects.
General Site Work and Ongoing Monitoring
- ARCO is working with the U.S.
Department of Agriculture Forest Service (USFS) to secure part of the land
needed for the permanent solids repository and water treatment cells under
the Small Tracts Act. EPA and USFS have coordinated on this topic. A
portion of land acquisition is complete, and the application has been
submitted for the remaining portion.
- Pond berms, spillways, outlet pipes, and freeboard are
inspected monthly and deficiencies, primarily due to beaver activity, are
corrected as needed.
- A weather station was installed in November 2014 to
measure evaporation, precipitation, temperature, wind speed/direction,
humidity, barometric pressure, and snow depth. A telemetry system transmits
the weather station data and other Site data so the information and Site
photos are viewable via Internet.
- Continuous (hourly) flow measurements are made at the
St Louis Tunnel discharge downstream of the historic portal (station DR-3)
and at the pond system outfall (DR-6) to the Dolores River using automated
instrumentation. The DR-3 flow data is transmitted via the telemetry
system for remote viewing.
- Water samples are collected seasonally (high flow,
moderate/low flow, and low flow) from the St. Louis Tunnel discharge, two
points within the pond system (discharge from Ponds 8 and 15), the outfall
from the pond system to the Dolores River, and five locations in the
Dolores River upstream, adjacent to, and downstream of the St. Louis
settling pond system.
- Groundwater
samples are collected and water levels are measured seasonally in
monitoring wells (including some paired shallow/deep wells) located
throughout the Site. Water levels are measured monthly in select wells.
- Continuous (hourly) pressure measurements are made at
the St Louis Tunnel via monitoring wells AT-2 and BAH-01. During 2015 the
readings were linked to Site telemetry to allow regular review and
interpretation of the data.
Solids and Water Management
- Precipitation solids from historic lime addition water
treatment were removed from the ponds and placed in the Interim Drying
Facility (IDF) drying cells, located in the former Pond 16/17 area, to
increase pond storage capacity, reduce the potential for releases to the
Dolores River, and facilitate construction of water treatment units. During
2015 the solids from Ponds 14 and 18 were consolidated with other pond
solids in IDF and are awaiting placement in the solids repository.
Approximately 35,900 cubic yards (cy) of treatment solids and calcines
combined are staged onsite.
Treatment solids are drying and awaiting placement in the solids
repository. Calcines may also be placed in the repository or potentially
used as structural fill onsite.
- Calcines,
a solid waste from roasting pyrite ore to produce sulfuric acid,
are present at many Site locations including the former Pond 16/17 area, beneath
Pond 13, between Pond 19 and the Voluntary Clean-up Plan (VCUP) soils
repository, and elsewhere. In-place calcines were tested to determine if
drainage from the lime precipitation solids or groundwater flowing through the
calcines causes leaching of hazardous substances and potential migration
off-site. Results to date indicate that
the calcines are not contributing significantly to off-site releases associated
with ground water; localized elevated levels of heavy metals are observed. Calcines were excavated during installation
of the demonstration scale wetland in 2013 and stockpiled on Site. Additional
calcines were excavated from the Pond 18 and Pond 14 areas during 2015 Expanded
Wetland Demonstration system installation. Excavated calcines were tested to
determine if they are suitable for use as fill in limited circumstances, such
as fill for construction of lined wetland cell berms. If a suitable use can be
found for these materials, the repository lifetime will be extended and the
need for importing off-site fill material will be reduced.
- A lined solids repository (Phase 1) was designed and
constructed during 2014 and 2015. The Phase 1 cell is designed for
approximately 30,000 cy of waste. The repository design allows for
expansion into the Pond 16/17 area, if needed, for a full build-out
storage capacity of 365,000 cy. A Land Use Application and an Engineering
Design and Operations Plan were submitted to EPA, the State of Colorado,
and Dolores County. A Certificate of Designation was approved by Dolores
County in March 2015 pursuant to state solid waste regulations. (While a
CD/permit is not required as part of the CERCLA action, long-term
regulatory control is anticipated to fall under the state solid waste
program.)
-
Repository construction
began during June 2014 and was completed in 2015. Solids will be placed in the
repository during 2016 for disposal. Soil excavated from the repository
footprint was screened to provide road base and soil for other Site uses.
-
The Site access
road was realigned to the west of the repository footprint. Power and
communications lines in the vicinity of the solids repository were buried along
the new access road.
- Pond berms were evaluated during 2011-2013. The flood dike,
forming the west bank of the settling ponds adjacent to the Dolores River,
was upgraded in June 2012 based on 100-year flood modeling (HEC-RAS).
Upgrades included: dike embankment filter material was added near seeps, larger
and more riprap was added near the upper ponds (18 and 15), and the elevation
of the dike along Pond 9 was increased to provide more freeboard.
- In
2013 a buried pipe that posed stability concerns was identified in Pond 18.
Pond 15 discharge structures were upgraded during 2015 along with Pond 14
headgates and piping. Pond 18 and Pond 14 berms were reconfigured and
upgraded in 2015 during Enhanced Wetland Demonstration system
installation.
Hydraulic Controls at St. Louis
Tunnel Collapsed Adit Area and Mine Water Source Control
- The collapsed portion of the exposed St. Louis Tunnel
extends approximately 250 feet from the concrete portal to the buried section
of tunnel overlain by loosely consolidated (sand to boulder size) colluvium.
The collapse (“debris plug”) extends into the unexposed portion of the
tunnel. The “terrain trap,” as this area is referred to, presents a difficult
and unsafe condition in which to attempt opening the tunnel or to
construct controls to capture the mine water flowing from the tunnel
through a debris plug. Two borings (AT-2 and BAH-01) were drilled through
bedrock into the tunnel. The water levels and associated pressure on the
blockage are monitored through the bore holes and are available real-time via
telemetry.
-
Recent
inconsistencies between BAH-01 and AT-2 water levels during 2015 indicate that
the debris plug may be more extensive than previously thought. Also, flows and water levels in the tunnel are
being compared to assess potential changes in the permeability of the blockage.
Siphon/drawdown/recovery step tests were performed on AT-2, and approximately
2.2 million gallons were siphoned from the mine pool as of December 1, 2015.
Water levels will be monitored and additional hydraulic controls installed as
needed to maintain the mine pool below a level of concern.
-
Hydraulic control
alternatives and potential failure modes were analyzed by ARCO. A model was
developed in 2013 to assist in determining the anticipated flow from the St.
Louis Tunnel before and after hydraulic controls are installed. A system to
pump water from well AT-2, located approximately 260 feet behind the former
portal structure and 50 feet behind the open collapsed adit, was installed
during 2014 (Hydraulic Controls Phase 1). The system includes a pipe to
transport pumped water to the DR-3 flume channel. During 2016 a pipe will be
installed to carry water through the collapsed adit (Hydraulic Controls Phase
2).
- Underground
mine workings investigations were performed in select portions of the
extended mine workings during 2011, 2012, and 2015 to assess in-mine water
chemistry, flow pathways, and the structural conditions of workings. DRMS developed
recommendations for rehabilitation needed to ensure access and continued
transport of water to the St. Louis Tunnel. EPA, Colorado DRMS, and ARCO
supported these efforts.
- The
517 Shaft and Blaine Adit portals were reconstructed in 2012 to provide
structurally safe conditions to enter the adits. The portals and the
initial sections of the adits were replaced with steel supports and steel
lagging.
- In
the Blaine Adit, the existing coffer dam, approximately 350 feet
inside was replaced in 2013 to
ensure that acid mine water continues to flow down the workings and
ultimately into the 517 Shaft and does
not discharge from the adit to Silver Creek. The previous dam showed
evidence of corrosion when the mine pool was drained for work in the adit
in 2012.
- A
flume was installed in the Blaine Adit to measure the flow of water from
the workings entering into the 517 Shaft via the Humboldt Drift. A
pressure transducer was installed to measure flow through the flume and
readings began in October 2012.
- Blockages
from rock falls in the Blaine Tunnel that were impeding flow to the
Morris Cook Incline were removed to allow flow to continue towards the 517
Shaft. A portion of one of the blockages in the Humbolt Drift remains due
to the ground / rubble that created an unsafe condition to continue without
substantially more work. Water is flowing as needed towards the Morris
Cook Incline.
- A pool in the Argentine Mine Adit
was sampled in 2011 and 2015. Extremely high metals concentrations point
to this as a potentially significant source of contaminants discharging
from the St. Louis Tunnel. In addition, flow measurements were conducted
with DRMS and the conditions were evaluated in 2015 to determine the
feasibility of conducting a tracing test within the mine. Metals loading from the Argentine Mine
to the St. Louis Tunnel may be assessed during 2016 in coordination with
ARCO. However, underground mine contractor support is required to conduct
this work including DRMS contracting efforts.
- An Evaluation of Source Water Controls Report was
prepared by ARCO in December 2013, and a revised report addressing EPA
comments was submitted to EPA in October 2014. Mine water source controls
beyond those described above appear to be an unlikely option at this time
based on the conditions of the underground workings.
Water Treatment (St. Louis Tunnel
mine drainage)
- A semi-passive
bio-chemical water treatment system was selected for testing at the Site.
A series of systems have been installed including pilot scale,
demonstration scale and large scale (~ 500 gpm) for testing at the Site. The treatment systems include settling basins,
bioreactors, aeration channels, and manganese removal cells. Details of
the different systems are described below. The demonstration systems are
being evaluated to confirm the performance and design features. To date, the metals removal efficiencies
have been highly effective. Pending the results of the large scale system,
Enhanced Demonstration Wetland (EDW), performance over the winter and
during the run-off/ freshet, a decision will be made on the final design
and build-out of the system. Currently, active lime treatment is the
default treatment technology if the results of the bio-reactor testing do
not demonstrate adequate reliability to meet potential discharge criteria.
- A
significant advantage of the semi-passive, bio-reactor system is the
operational stability over winter months without active onsite
management. Avalanche risk onsite
and access difficulty present significant challenges to operating active
treatment systems in remote mountain locations. In addition, the reduced
waste volume is a significant advantage to the bio-reactor cell, which is
expected to operate without replacing the treatment matrix for 5 to 15
years.
- Pilot
scale (1 to 10 gpm) was installed in 2013 and operated for over a
year. The results from the pilot scale
unit were reported in a previous Polrep and other reporting.
- The demonstration
scale (10 to 50 gpm) passive water treatment systems were
tested at the Site from 2014 through 2015. The demonstration scale system includes both a horizontal flow
treatment train and a vertical flow biochemical reactor cell with pre-treatment
train, each designed for 50 gpm. The two systems were installed to allow a
comparison of performance and design considerations, especially comparing
the horizontal and vertical flow bio-reactors. Water discharged from the
vertical and horizontal flow systems has dissolved cadmium concentrations
below the detection limit and zinc removal efficiencies consistently greater
than 98 percent. Manganese removal efficiencies of up to 98 percent were
observed in the horizontal flow system that includes the rock drain. The demonstration
scale treatment components are as follows:
The
horizontal flow system includes:
-
Settling basin to remove solids and iron, with
aluminum chlorohydrate added to assist in particulate coagulation
-
Surface flow
wetland containing soil and
plants for additional iron removal
-
Horizontal
subsurface flow wetland containing rock, wood chips, manure, sulfur prills, fish fertilizer, and
sulfate-reducing bacteria to reduce metals in water to solid metal sulfides
-
Aeration
channel to oxygenate the
wetland discharge
-
Rock drain containing rock and organisms to remove
manganese
The
vertical flow system includes :
-
Settling basin (same as horizontal flow) to remove solids and iron, with aluminum chlorohydrate added to assist in particulate coagulation.
-
Vertical flow
biotreatment cell containing wood chips, wood shavings, manure, hay, and sulfate reducing
bacteria to reduce metals in water to solid metal sulfides
-
Aeration
cascade to oxygenate the
wetland discharge
The demonstration wetland system was
completed in August 2014 and was commissioned at 30 gpm during early September
2014; sampling began on September 16, 2014. System testing began after
monitoring showed that the organisms responsible for anaerobic metal reduction
and manganese precipitation were stable. Flow, water levels, temperature, pH,
oxidation reduction potential, conductivity, hydrogen sulfide concentrations, and
vegetation characteristics are monitored. The telemetry system provides remote
access to key data. Samples are collected regularly at the inlet and outlet to
each treatment unit.
The demonstration systems will continue
to operate as long as practical to help identify long-term operations and
maintenance and disposal requirements.
- An Enhanced Wetland Demonstration (EWD) system was
designed and constructed in 2015 to treat up to 550 gpm of mine discharge based
on the results of the demonstration wetland testing. The EWD was installed
in the Pond 18 and 14 areas and commissioned in 2015. The EWD includes a settling
pond, manganese removal cell, vertical flow bioreactor, and aeration
channel. Sensor equipment measures flow,
water levels, temperature, pH, oxidation reduction potential,
conductivity, hydrogen sulfide concentrations, which are monitored via
telemetry system that provides remote access.. Water samples are collected
regularly at the inlet and outlet to each treatment unit.
- A pilot scale in-situ (517 Shaft injection) water
treatment test was conducted during 2012 and 2013. Potassium carbonate and
sodium hydroxide were injected into the 517 Shaft to treat water. The test
resulted in improved discharge water quality at the St. Louis Tunnel. While
treatment in the shaft is feasible, the long-term operation poses
technical challenges that have not been addressed. These studies did
provide additional information as to the source of metals loads with the
respective cross-cuts connecting to the St. Louis Tunnel.
- Bench scale ion exchange water treatment tests were
conducted on Blaine Tunnel and St. Louis Tunnel waters during 2012, and
ion exchange resins, effective for removing contaminants from each water
source, were identified.
2.1.3
Enforcement Activities, Identity of Potentially Responsible Parties (PRPs)
- A
Unilateral Administrative Order (UAO) was issued to the Atlantic Richfield
Company (ARCO) in May 2011 to implement the Removal Action specified in
the Work Plan.
2.1.4 Progress Metrics
Waste Stream |
Medium |
Quantity |
Manifest # |
Treatment |
Disposal |
Pond 18 - 2011 |
Lime precipitates |
7500 cy |
NA |
NA |
Pond 16/17 drying cells (IDF) |
Pond 18 - 2014 |
Lime precipitates and calcines |
8100 cy |
NA |
NA |
Pond 13 and IDF |
Pond 15 - 2012 |
Lime precipitates |
3500 cy |
NA |
NA |
Pond 13 |
Pond 11 and 12 - 2013 |
Lime precipitates |
5700 cy |
NA |
NA |
Pond 13 |
Pond 14 - 2014 |
Lime precipitates and calcines |
1400 cy |
NA |
NA |
Pond 13 |
Pond 14 - 2015 |
Lime precipitates and calcines |
1700 cy |
NA |
NA |
Pond 13 |
Demonstration Wetland Area |
Lime precipitates and calcines |
8000 cy |
NA |
NA |
IDF and north staging area |
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